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Title: Thermolytic reactions of esters. Part XIII. The effect of electron attracting α-substituents in alkyl acetates
Journal: Rec. Trav. Chim. Pays/Bas
Volume: 102
Page(s):
Year: 1983
Reference type: Journal article
Squib: 1983LOU/TIN519
Reaction:
CH3C(O)OC(CN)(CH3)2 → CH3C(O)OH + CH2=C(CH3)CN
Reaction order:
1
Temperature:
640 - 713
K
Rate expression:
7.94x1011 [s-1] e-167952 [J/mole]/RT
Uncertainty:
2.0
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 640 | 1.56E-2 |
| 650 | 2.53E-2 |
| 675 | 8.00E-2 |
| 700 | 2.33E-1 |
| 713 | 3.94E-1 |