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Author(s):   Adamczyk, A.J.; Reyniers, M.F.; Marin, G.B.; Broadbelt, L.J.
Title:   Kinetic correlations for H2 addition and elimination reaction mechanisms during silicon hydride pyrolysis
Journal:   Phys. Chem. Chem. Phys.
Volume:   12
Page(s):   12676 - 12696
Year:   2010
Reference type:   Journal article
Squib:   2010ADA/REY12676-12696

Reaction:   SiH3SiH2SiH: + H2Si3H8
Reaction order:   2
Temperature:   800 - 1200 K
Rate expression:   1.0x10-11 [cm3/molecule s] e-8786 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory
Pressure dependence:   Rate constant is high pressure limit
Comments:   Reaction potential energy surface was studied using quantum chemistry and rate constants were calculated using transition state theory.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
800 2.67E-12
825 2.78E-12
850 2.88E-12
875 2.99E-12
900 3.09E-12
925 3.19E-12
950 3.29E-12
975 3.38E-12
1000 3.48E-12
1025 3.57E-12
1050 3.66E-12
1075 3.74E-12
1100 3.83E-12
1125 3.91E-12
1150 3.99E-12
1175 4.07E-12
1200 4.15E-12