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Title: Temperature Dependence of the Rate Coefficients for the Reactions of Atomic Bromine with Toluene, Tetrahydrofuran, and Tetrahydropyran
Journal: J. Phys. Chem. A
Volume: 113
Page(s): 8001 - 8010
Year: 2009
Reference type: Journal article
Squib: 2009GIR/ROS8001-8010
Reaction:
Toluene + Br· → Products
Reaction order:
2
Reference reaction:
iso-C4H10 + Br· → Products
Temperature:
302 - 352
K
Pressure: 1.01 - 1.01 bar
Rate expression:
3.7x10-12 [±1.7x10-12 cm3/molecule s] e-13553 [±1247 J/mole]/RT
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
Rate constant is pressure independent
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Gas chromatography
Comments:
Experiments were performed in a bath of argon containing unspecified but varied amount of oxygen. The uncertainties represent one standard deviation.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 302 | 1.68E-14 |
| 325 | 2.45E-14 |
| 350 | 3.51E-14 |
| 352 | 3.61E-14 |