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Accessibility information
Author(s):   Thynne, J.C.j.
Title:   Reactions of alkyl radicals. Part 1.-Methyl radical photosensitized decomposition of ethyl formate
Journal:   Trans. Faraday Soc.
Volume:   58
Year:   1962
Reference type:   Journal article
Squib:   1962THY676

Reaction:   HC(O)OC2H5 + ·CH3CH4 + CH3CH2OC(O)·
Reaction order:   2
Reference reaction:   ·CH3 + ·CH3C2H6
Temperature:   370 - 521 K
Pressure:  7.33E-2 - 0.17 bar
Rate expression:   5.25x10-14 [cm3/molecule s] e-34339 [J/mole]/RT
Bath gas:   HC(O)OC2H5
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Sensitized photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
370 7.45E-19
375 8.65E-19
400 1.72E-18
425 3.16E-18
450 5.42E-18
475 8.79E-18
500 1.36E-17
521 1.89E-17