Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article

Citation

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Swihart, M.T.; Carr, R.W.
Title:   On the mechanism of homogeneous decomposition of the chlorinated silanes. Chain reactions propagated by divalent silicon species
Journal:   J. Phys. Chem. A
Volume:   102
Page(s):   1542 - 1549
Year:   1998
Reference type:   Journal article
Squib:   1998SWI/CAR1542-1549

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1998SWI/CAR1542-1549   SiHCl3HCl + SiCl2  800 - 1300   5.01E14       3.00E05      1
  1998SWI/CAR1542-1549   SiHCl3HCl + SiCl2  800 - 1300   3.99E-07       2.37E05      2
  1998SWI/CAR1542-1549   Si2Cl6SiCl4 + SiCl2  800 - 1300   1.58E14       2.05E05      1
  1998SWI/CAR1542-1549   SiH3ClH2 + SiHCl  800 - 1300   1.00E15       2.89E05      1
  1998SWI/CAR1542-1549   SiH3ClH2 + SiHCl  800 - 1300   2.51E-07       2.41E05      2
  1998SWI/CAR1542-1549   Si2H5Cl → SiH3Cl + SiH2  800 - 1300   1.58E14       1.98E05      1
  1998SWI/CAR1542-1549   Si2H5Cl → Other Products + H2  800 - 1300   2.51E14       2.25E05      1
  1998SWI/CAR1542-1549   Si2H5Cl → SiH4 + SiHCl  800 - 1300   2.51E13       2.05E05      1
  1998SWI/CAR1542-1549   SiH2=SiH2SiH2 + SiH2  800 - 1300   1.00E15       2.54E05      1
  1998SWI/CAR1542-1549   Si2H6H2 + SiH2=SiH2  800 - 1300   5.01E14       2.30E05      1
  1998SWI/CAR1542-1549   Si2H6SiH4 + SiH2  800 - 1300   3.16E14       1.90E05      1
  1998SWI/CAR1542-1549   H3Si-SiHCl2SiH3Cl + SiHCl  800 - 1300   6.31E13       2.18E05      1
  1998SWI/CAR1542-1549   H3Si-SiHCl2 → Other Products + H2  800 - 1300   2.51E14       2.24E05      1
  1998SWI/CAR1542-1549   H3Si-SiHCl2SiH2Cl2 + SiH2  800 - 1300   1.26E14       2.09E05      1
  1998SWI/CAR1542-1549   H3Si-SiHCl2SiH4 + SiCl2  800 - 1300   2.00E13       2.25E05      1
  1998SWI/CAR1542-1549   SiHCl2SiH2Cl → SiHCl3 + SiH2  800 - 1300   1.26E13       2.13E05      1
  1998SWI/CAR1542-1549   SiHCl2SiH2Cl → SiH3Cl + SiCl2  800 - 1300   1.26E13       2.06E05      1
  1998SWI/CAR1542-1549   SiHCl2SiH2Cl → Other Products + H2  800 - 1300   7.94E13       2.29E05      1
  1998SWI/CAR1542-1549   SiHCl2SiH2Cl → SiH2Cl2 + SiHCl  800 - 1300   3.98E13       1.96E05      1
  1998SWI/CAR1542-1549   SiH2Cl2H2 + SiCl2  800 - 1300   7.94E13       3.20E05      1
  1998SWI/CAR1542-1549   SiH2Cl2H2 + SiCl2  800 - 1300   2.51E-10       2.69E05      2
  1998SWI/CAR1542-1549   SiH2Cl2HCl + SiHCl  800 - 1300   7.94E14       3.13E05      1
  1998SWI/CAR1542-1549   SiH2Cl2HCl + SiHCl  800 - 1300   5.01E-07       2.59E05      2
  1998SWI/CAR1542-1549   SiH4H2 + SiH2  800 - 1300   5.01E14       2.53E05      1
  1998SWI/CAR1542-1549   SiH4H2 + SiH2  800 - 1300   7.95E-08       2.15E05      2

Search returned 25 records.