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Title: Reactions of trifluoromethyl radicals with propane, n-butane and isobutane
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 69
Page(s):
Year: 1973
Reference type: Journal article
Squib: 1973ARI/POT1811
Reaction:
C3H8 + ·CF3 → CHF3 + 2-C3H7
Reaction order:
2
Temperature:
318 - 505
K
Pressure: 9.40E-2 - 0.13 bar
Rate expression:
3.02x10-13 [cm3/molecule s] e-27271 [J/mole]/RT
Bath gas:
CF3I
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 318 | 1.00E-17 |
| 325 | 1.25E-17 |
| 350 | 2.57E-17 |
| 375 | 4.80E-17 |
| 400 | 8.30E-17 |
| 425 | 1.34E-16 |
| 450 | 2.06E-16 |
| 475 | 3.03E-16 |
| 500 | 4.28E-16 |
| 505 | 4.57E-16 |