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Accessibility information
Author(s):   Arican, M.H.; Potter, E.; Whytock, D.A.
Title:   Reactions of trifluoromethyl radicals with propane, n-butane and isobutane
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   69
Page(s):  
Year:   1973
Reference type:   Journal article
Squib:   1973ARI/POT1811

Reaction:   C3H8 + ·CF3CHF3 + 2-C3H7
Reaction order:   2
Reference reaction:   C3H8 + ·CF3CHF3 + 1-C3H7
Reference reaction order:   2
Temperature:   318 - 505 K
Pressure:  9.40E-2 - 0.13 bar
Rate expression:   3.4x10-1 e8564 [±856 J/mole]/RT
Uncertainty:   1.23000002
Bath gas:   CF3I
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
318 8.67E0
325 8.09E0
350 6.45E0
375 5.30E0
400 4.46E0
425 3.84E0
450 3.35E0
475 2.97E0
500 2.67E0
505 2.61E0