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Accessibility information
Author(s):   Baldwin, R.R.; Drewery, G.R.; Walker, R.W.
Title:   Decomposition of 2,3-dimethylbutane in the presence of oxygen. Part 2.-Elementary reactions involved in the formation of products
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   80
Year:   1984
Reference type:   Journal article
Squib:   1984BAL/DRE3195

Reaction:   (CH3)2CHC(·)(CH3)2 → (CH3)2C=CHCH3 + ·CH3
Reaction order:   1
Temperature:   773 - 813 K
Pressure:  7.33E-3 - 0.17 bar
Rate expression:   6.31x1013 [s-1] e-129706 [±6477 J/mole]/RT
Bath gas:   O2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
773 1.09E5
775 1.14E5
800 2.14E5
813 2.93E5