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Accessibility information
Author(s):   Clyne, M.A.A.; McKenney, D.J.; Walker, R.F.
Title:   Reaction kinetics of ground state fluorine, F(2P), atoms. I. Measurement of fluorine atom concentrations and the rates of reactions F + CHF3 and F + Cl2 using mass spectrometry
Journal:   Can. J. Chem.
Volume:   51
Year:   1973
Reference type:   Journal article
Squib:   1973CLY/MCK3596

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1973CLY/MCK3596   CHCl3 + ·F·CCl3 + HF  298   5.30E-12           5.30E-12  2
  1973CLY/MCK3596   CH4 + ·F·CH3 + HF  298   5.99E-11           5.99E-11  2
  1973CLY/MCK3596   CH3Cl + ·F·CH2Cl + HF  298   2.41E-11           2.41E-11  2
  1973CLY/MCK3596   CH2Cl2 + ·FCHCl2 + HF  298   9.60E-12           9.60E-12  2
  1973CLY/MCK3596   CHF3 + ·F·CF3 + HF  301 - 667   1.05E-11       4348      2
  1973CLY/MCK3596   H2 + ·FHF +   298   2.51E-11           2.51E-11  2
  1973CLY/MCK3596   Cl2 + ·FClF + ·Cl  300   1.10E-10              2

Search returned 7 records.