Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Clyne, M.A.A.; McKenney, D.J.; Walker, R.F.
Title:   Reaction kinetics of ground state fluorine, F(2P), atoms. I. Measurement of fluorine atom concentrations and the rates of reactions F + CHF3 and F + Cl2 using mass spectrometry
Journal:   Can. J. Chem.
Volume:   51
Page(s):  
Year:   1973
Reference type:   Journal article
Squib:   1973CLY/MCK3596

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1973CLY/MCK3596   CHCl3 + ·F·CCl3 + HF  298   5.30E-12           5.30E-12  2
  1973CLY/MCK3596   CH4 + ·F·CH3 + HF  298   5.99E-11           5.99E-11  2
  1973CLY/MCK3596   CH3Cl + ·F·CH2Cl + HF  298   2.41E-11           2.41E-11  2
  1973CLY/MCK3596   CH2Cl2 + ·FCHCl2 + HF  298   9.60E-12           9.60E-12  2
  1973CLY/MCK3596   CHF3 + ·F·CF3 + HF  301 - 667   1.05E-11       4348      2
  1973CLY/MCK3596   H2 + ·FHF +   298   2.51E-11           2.51E-11  2
  1973CLY/MCK3596   Cl2 + ·FClF + ·Cl  300   1.10E-10              2

Search returned 7 records.