Kinetics Database Logo     Home
©NIST, 2023
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article



Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Sawrey, B.A.; O'Neal, H.E.; Ring, M.A.; Coffey, D., Jr.
Title:   The gas-phase decomposition of methylsilane. Part I. Mechanism of decomposition under shock-tube conditions
Journal:   Int. J. Chem. Kinet.
Volume:   16
Page(s):   7 - 21
Year:   1984
Reference type:   Journal article
Squib:   1984SAW/ONE7-21

Reaction:   CH3SiD3D2 + CH3DSi:
Reaction order:   1
Reference reaction:   CH3SiD3 → Products
Reference reaction order:   1
Temperature:   1120 - 1250 K
Pressure:  6.27 bar
Rate expression:   7.1x10-1±5.7x10-2
Bath gas:   CH3SiD3
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.