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Title: Kinetics of the gas-phase reactions of OH radicals with alkanes and cycloalkanes
Journal: Atmos. Chem. Phys.
Volume: 3
Page(s): 2233 - 2307
Year: 2003
Reference type: Journal article
Squib: 2003ATK2233-2307
Reaction:
neo-C5H12 + ·OH → Neopentyl + H2O
Reaction order:
2
Temperature:
280 - 910
K
Rate expression:
1.65x10-12 [cm3/molecule s] (T/298 K)2.00 e-1721 [J/mole]/RT
Category: Review
Data type:
Extensive literature review
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 280 | 6.96E-13 |
| 300 | 8.40E-13 |
| 350 | 1.26E-12 |
| 400 | 1.77E-12 |
| 450 | 2.38E-12 |
| 500 | 3.07E-12 |
| 550 | 3.86E-12 |
| 600 | 4.74E-12 |
| 650 | 5.72E-12 |
| 700 | 6.78E-12 |
| 750 | 7.94E-12 |
| 800 | 9.19E-12 |
| 850 | 1.05E-11 |
| 900 | 1.20E-11 |
| 910 | 1.23E-11 |