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Author(s):   Borrell, P.; Platt, A.E.
Title:   Photolysis of tetramethylstannane vapour at 185 nm
Journal:   Trans. Faraday Soc.
Volume:   66
Page(s):   2286 - 2296
Year:   1970
Reference type:   Journal article
Squib:   1970BOR/PLA2286-2296

Reaction:   (CH3)4Sn + ·CH3C2H6 + (CH3)3Sn
Reaction order:   2
Temperature:   298 - 423 K
Pressure:  2.71E-2 bar
Rate expression:   4.27x10-17 [cm3/molecule s] e-5496 [J/mole]/RT
Bath gas:   (CH3)4Sn
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 4.64E-18
300 4.71E-18
325 5.58E-18
350 6.46E-18
375 7.32E-18
400 8.18E-18
423 8.94E-18