Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2020 Accessibility information |
Title: Thermolytic reactions of esters. Part V. Thermal stability of diallyl oxalate vapour; reactivity of allyl radicals
Journal: Recueil
Volume: 90
Page(s):
Year: 1971
Reference type: Journal article
Squib: 1971LOU469
Reaction:
Toluene + ·CH2CH=CH2 → CH3CH=CH2 + Benzyl
Reaction order:
2
Temperature:
653 - 784
K
Pressure: 1.01 bar
Rate expression:
1.66x10-13 [cm3/molecule s] e-66931 [±8730 J/mole]/RT
Bath gas:
Toluene
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 653 | 7.35E-19 |
| 675 | 1.10E-18 |
| 700 | 1.68E-18 |
| 725 | 2.50E-18 |
| 750 | 3.62E-18 |
| 775 | 5.12E-18 |
| 784 | 5.77E-18 |