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Title: The pyrolysis and subsequent oxidation of SF6
Journal: Symp. Int. Combust. Proc.
Volume: 14
Page(s):
Year: 1973
Reference type: Journal article
Squib: 1973WRA/FEL229
Reaction:
SF6 → SF5 + ·F
Reaction order:
1
Temperature:
1000 - 2200
K
Pressure: 1.33E-2 - 0.13 bar
Rate expression:
3.6x1011 [s-1] e-292669 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1000 | 1.86E-4 |
| 1100 | 4.56E-3 |
| 1200 | 6.56E-2 |
| 1300 | 6.27E-1 |
| 1400 | 4.33E0 |
| 1500 | 2.32E1 |
| 1600 | 1.00E2 |
| 1700 | 3.66E2 |
| 1800 | 1.16E3 |
| 1900 | 3.24E3 |
| 2000 | 8.18E3 |
| 2100 | 1.89E4 |
| 2200 | 4.05E4 |