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Author(s):   Wray, K.L.; Feldman, E.V.
Title:   The pyrolysis and subsequent oxidation of SF6
Journal:   Symp. Int. Combust. Proc.
Volume:   14
Year:   1973
Reference type:   Journal article
Squib:   1973WRA/FEL229

Reaction:   SF6SF5 + ·F
Reaction order:   1
Temperature:   1000 - 2200 K
Pressure:  1.33E-2 - 0.13 bar
Rate expression:   3.6x1011 [s-1] e-292669 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 1.86E-4
1100 4.56E-3
1200 6.56E-2
1300 6.27E-1
1400 4.33E0
1500 2.32E1
1600 1.00E2
1700 3.66E2
1800 1.16E3
1900 3.24E3
2000 8.18E3
2100 1.89E4
2200 4.05E4