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Author(s):   Pritchard, G.O.; Perona, M.J.
Title:   Some hydrogen atom abstraction reactions of CF2H and CFH2 radicals, and the C-H bond dissociation energy in CF2H2
Journal:   Int. J. Chem. Kinet.
Volume:   1
Page(s):   509 - 525
Year:   1969
Reference type:   Journal article
Squib:   1969PRI/PER509-525

Reaction:   (CH2F)2CO + ·CH2FCH3F + CH2FC(O)CHF·
Reaction order:   2
Reference reaction:   ·CH2F + ·CH2FCH2FCH2F
Temperature:   410 - 562 K
Rate expression:   1.51x10-12 [cm3/molecule s] e-43900 [J/mole]/RT
Bath gas:   (CH2F)2CO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
410 3.87E-18
425 6.09E-18
450 1.21E-17
475 2.25E-17
500 3.93E-17
525 6.49E-17
550 1.03E-16
562 1.26E-16