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Author(s):   Diaz, R.R.; Selby, K.; Waddington, D.J.
Title:   Reactions of Oxygenated Radicals in the Gas Phase. Part 3. Reactions of Peracetyl Radicals with Alkenes
Journal:   J. Chem. Soc. Perkin Trans. 2
Volume:   3
Year:   1977
Reference type:   Journal article
Squib:   1977DIA/SEL360

Reaction:   CH3C(O)OOH + (CH3)2C=CHCH3CH3C(O)OH + 2,2,3-trimethyl-oxirane
Reaction order:   2
Temperature:   370 - 410 K
Pressure:  0.28 bar
Rate expression:   2.82x10-13 [cm3/molecule s] e-61610 [±2461 J/mole]/RT
Uncertainty:   2.1400001
Bath gas:   O2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
370 5.66E-22
375 7.40E-22
400 2.54E-21
410 4.00E-21