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Title: Reactions of Oxygenated Radicals in the Gas Phase. Part 3. Reactions of Peracetyl Radicals with Alkenes
Journal: J. Chem. Soc. Perkin Trans. 2
Volume: 3
Page(s):
Year: 1977
Reference type: Journal article
Squib: 1977DIA/SEL360
Reaction:
CH3C(O)OOH + (CH3)2C=CHCH3 → CH3C(O)OH + 2,2,3-trimethyl-oxirane
Reaction order:
2
Temperature:
370 - 410
K
Pressure: 0.28 bar
Rate expression:
2.82x10-13 [cm3/molecule s] e-61610 [±2461 J/mole]/RT
Uncertainty:
2.1400001
Bath gas:
O2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 370 | 5.66E-22 |
| 375 | 7.40E-22 |
| 400 | 2.54E-21 |
| 410 | 4.00E-21 |