Author(s):   Howard, C.J.; Evenson, K.M.
Title:   Rate Constants for the Reactions of OH with CH₄ and Fluorine, Chlorine, and Bromine Substituted Methanes at 296K
Journal:   J. Chem. Phys.
Volume:   64
Page(s):
Year:   1976
Reference type:   Journal article
Squib:   1976HOW/EVE197

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Order
1976HOW/EVE197	CCl₄ + ·OH → Products	296	<4.00E-15	2
1976HOW/EVE197	CHCl₃ + ·OH → ·CCl₃ + H₂O	296	1.01E-13	2
1976HOW/EVE197	CH₄ + ·OH → ·CH₃ + H₂O	296	9.51E-15	2
1976HOW/EVE197	CH₃Br + ·OH → H₂O + ·CH₂Br	296	3.50E-14	2
1976HOW/EVE197	CH₃Cl + ·OH → ·CH₂Cl + H₂O	296	3.60E-14	2
1976HOW/EVE197	CH₂Cl₂ + ·OH → CHCl₂ + H₂O	296	1.55E-13	2
1976HOW/EVE197	CH₂F₂ + ·OH → ·CHF₂ + H₂O	296	7.80E-15	2
1976HOW/EVE197	CHFCl₂ + ·OH → ·CCl₂F + H₂O	296	2.61E-14	2
1976HOW/EVE197	CHF₂Cl + ·OH → ·CClF₂ + H₂O	296	3.40E-15	2
1976HOW/EVE197	CHF₃ + ·OH → ·CF₃ + H₂O	296	2.01E-16	2
1976HOW/EVE197	CFCl₃ + ·OH → Products	296	<5.00E-16	2
1976HOW/EVE197	CF₂Cl₂ + ·OH → Products	296	<4.00E-16	2
1976HOW/EVE197	CF₃Cl + ·OH → Products	296	<7.01E-16	2
1976HOW/EVE197	CF₄ + ·OH → Products	296	<4.00E-16	2
1976HOW/EVE197	CH₃F + ·OH → ·CH₂F + H₂O	296	1.60E-14	2
1976HOW/EVE197	CH₂FCl + ·OH → H₂O + ·CClFH	296	3.70E-14	2

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