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Title: Theoretical calculation of thermochemistry, energetics, and kinetics of high-temperature SixHyOz reactions
Journal: J. Phys. Chem.
Volume: 99
Page(s): 5308 - 5318
Year: 1995
Reference type: Journal article
Squib: 1995ZAC/TSA5308-5318
Reaction:
SiO2 + H· → (·)Si(O)OH
Reaction order:
2
Temperature:
1000 - 2500
K
Pressure: 1.01 bar
Rate expression:
1.79x10-9 [cm3/molecule s] (T/298 K)-4.00 e-23696 [J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
RRK(M) extrapolation
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 1000 | 8.18E-13 |
| 1100 | 7.24E-13 |
| 1200 | 6.34E-13 |
| 1300 | 5.53E-13 |
| 1400 | 4.81E-13 |
| 1500 | 4.18E-13 |
| 1600 | 3.63E-13 |
| 1700 | 3.17E-13 |
| 1800 | 2.77E-13 |
| 1900 | 2.42E-13 |
| 2000 | 2.13E-13 |
| 2100 | 1.87E-13 |
| 2200 | 1.65E-13 |
| 2300 | 1.46E-13 |
| 2400 | 1.30E-13 |
| 2500 | 1.16E-13 |