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Author(s):   Garzon, A.; Antinolo, M.; Moral, M.; Notario, A.; Jimenez, E.; Fernandez-Gomez, M.; Albaladejo, J.
Title:   An experimental and theoretical study on the reaction of Cl with CF3CF2CH2OH
Journal:   Mol. Phys.
Volume:   111
Page(s):   753 - 763
Year:   2013
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2013GAR/ANT753-763

Reaction:   C2F5CH2OH + ·Cl → CF3CF2CH(·)OH + HCl
Reaction order:   2
Temperature:   270 - 370 K
Rate expression:   no rate data available
Category:  Theory
Data type:   Transition state theory
Pressure dependence:   Rate constant is pressure independent
Comments:   Reaction potential energy surface was studied using quantum chemistry and rate constants were calculated using transition state theory with tunneling correction. However, no Arrhenius expression is given for the k(T) dependence. Instead, rate constants for individual temperatures are presented in a tabular format.

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