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Accessibility information
Author(s):   Smith, D.J.; Setser, D.W.; Kim, K.C.; Bogan, D.J.
Title:   HF infrared chemiluminescence. Relative rate constants for hydrogen abstraction from hydrocarbons, substituted methanes, and inorganic hydrides
Journal:   J. Phys. Chem.
Volume:   81
Page(s):  
Year:   1977
Reference type:   Journal article
Squib:   1977SMI/SET898

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1977SMI/SET898   Acetone + ·FCH3C(O)CH2(·) + HF  298   1.60           1.60  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   Benzene + ·FPhenyl + HF  298   0.97           0.97  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   C2H6 + ·F·C2H5 + HF  298   2.10           2.10  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   C2H4 + ·FC2H3 + HF  298   0.52           0.52  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   CH3Cl + ·F·CH2Cl + HF  298   0.60           0.60  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   CH3CN + ·FCH2CN + HF  298   0.19           0.19  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   CH3CHO + ·F → Other Products + HF  298   1.60           1.60  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   CH2F2 + ·F·CHF2 + HF  298   <0.03           0.03  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   Cyclopropane + ·FCyclopropyl + HF  298   2.40           2.40  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   CHF3 + ·F·CF3 + HF  298   3.00E-03           3.00E-03  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   CH3NO2 + ·FHF + CH2NO2  298   0.09           0.09  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   Cyclohexane + ·FCyclohexyl + HF  298   4.30           4.30  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   (CH3)2O + ·FHF + CH3OCH2·  298   2.70           2.70  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   neo-C5H12 + ·FNeopentyl + HF  298   4.50           4.50  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   CH3F + ·F·CH2F + HF  298   0.48           0.48  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   H2 + ·FHF +   298   0.37           0.37  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   HCl + ·FHF + ·Cl  298   0.13           0.13  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   H2O2 + ·FHO2 + HF  298   0.10           0.10  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   GeH4 + ·FHF + GeH3  298   6.00           6.00  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   H2S + ·FHF + SH  298   2.00           2.00  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   SiH4 + ·FHF + SiH3  298   6.50           6.50  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   HI + ·FHF + I  298   0.74           0.74  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1977SMI/SET898   HBr + ·FHF + Br·  298   0.68           0.68  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2

Search returned 23 records.