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 Author(s):   Ganske, J.A.; Berko, H.N.; Ezell, M.J.; Finlayson-Pitts, B.J.
Title:   Kinetics of the gas-phase reaction of OH with ClNO2 from 259 to 348 K
Journal:   J. Phys. Chem.
Volume:   96
Page(s):   2568 - 2572
Year:   1992
Reference type:   Journal article
Squib:   1992GAN/BER2568-2572

Reaction:   ·OH + ClNO2 → HOCl + NO2
Reaction order:   2
Temperature:   259 - 348 K
Pressure:  1.33E-3 - 1.47E-3 bar
Rate expression:   2.41x10-12 [±1.39x10-12 cm3/molecule s] e-10393 [±1247 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
259 1.93E-14
275 2.56E-14
300 3.73E-14
325 5.14E-14
348 6.63E-14