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Author(s):   Tedder, J.M.; Watson, R.A.
Title:   Free radical substitution in aliphatic compounds. Part 11.-Reaction of trichloromethyl radicals with n-butane
Journal:   Trans. Faraday Soc.
Volume:   62
Year:   1966
Reference type:   Journal article
Squib:   1966TED/WAT1215

Reaction:   1-C4H10 + ·CCl3CHCl3 + sec-C4H9
Reaction order:   2
Reference reaction:   1-C4H10 + ·CCl3CHCl3 + 1-C4H9
Reference reaction order:   2
Temperature:   419 - 530 K
Pressure:  0.13 - 0.13 bar
Rate expression:   6.7x10-1 e15215 [J/mole]/RT
Bath gas:   1-C4H10
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
419 5.28E1
425 4.97E1
450 3.91E1
475 3.16E1
500 2.60E1
525 2.19E1
530 2.12E1