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Author(s):   Kerr, J.A.; Trotman-Dickenson, A.F.; Wolter, M.
Title:   Pyrolyses of NN-dimethylaniline, cumene, and phenylhydrazine, and bond strengths in aromatic amino-compounds
Journal:   J. Chem. Soc.
Year:   1964
Reference type:   Journal article
Squib:   1964KER/TRO3584

Reaction:   PhenylhydrazinePhenyl amidogen + ·NH2
Reaction order:   1
Temperature:   607 - 710 K
Pressure:  8.13E-3 - 1.71E-2 bar
Rate expression:   6.31x1011 [s-1] e-167121 [±8314472 J/mole]/RT
Bath gas:   Phenylhydrazine
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
607 2.62E-3
625 6.81E-3
650 2.35E-2
675 7.37E-2
700 2.14E-1
710 3.20E-1