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Accessibility information
Author(s):   Pang, G.A.; Hanson, R.K.; Golden, D.M.; Bowman, C.T.
Title:   Experimental Determination of the High-Temperature Rate Constant for the Reaction of OH with sec-Butanol
Journal:   J. Phys. Chem. A
Volume:   116
Page(s):   9607 - 9613
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012PAN/HAN9607-9613

Reaction:   sec-C4H9OH + ·OH → Products
Reaction order:   2
Temperature:   263 - 1178 K
Pressure:  0.96 - 1.26 bar
Rate expression:   1.89x10-13 [cm3/molecule s] (T/298 K)2.66 e9337 [J/mole]/RT
Category:  Experiment
Data type:   Experimental value and limited review
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   The quoted rate constant expression is derived from analysis of experimental data obtained in the current work and literature data at lower temperatures.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
263 9.69E-12
300 8.12E-12
350 7.17E-12
400 6.84E-12
450 6.85E-12
500 7.07E-12
550 7.43E-12
600 7.89E-12
650 8.46E-12
700 9.11E-12
750 9.83E-12
800 1.06E-11
850 1.15E-11
900 1.24E-11
950 1.35E-11
1000 1.45E-11
1050 1.57E-11
1100 1.69E-11
1150 1.82E-11
1178 1.90E-11