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Author(s):   Yang, D.L.; Yu, T.; Wang, N.S.; Lin, M.C.
Title:   Temperature dependence of cyanogen radical reactions with selected alkanes: CN reactivities towards primary, secondary and tertiary C-H bonds
Journal:   Chem. Phys.
Volume:   160
Page(s):   307 - 315
Year:   1992
Reference type:   Journal article
Squib:   1992YAN/YU307-315

Reaction:   CN + iso-C4H10HCN + tert-C4H9
Reaction order:   2
Temperature:   177 - 739 K
Rate expression:   3.25x10-12 [cm3/molecule s] (T/298 K)1.89 e5986 [J/mole]/RT
Bath gas:   Ar
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
177 7.10E-11
200 5.61E-11
250 4.16E-11
300 3.63E-11
350 3.45E-11
400 3.43E-11
450 3.51E-11
500 3.65E-11
550 3.84E-11
600 4.06E-11
650 4.30E-11
700 4.57E-11
739 4.80E-11