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Title: Bimolecular QRRK analyss of methyl radical reactions
Journal: Int. J. Chem. Kinet.
Volume: 19
Page(s):
Year: 1987
Reference type: Journal article
Squib: 1987DEA/WES207
Reaction:
C2H2 + ·CH3 → ·CH2CH=CH2
Reaction order:
2
Temperature:
900 - 2500
K
Pressure: 1.01 bar
Rate expression:
2.19x10-2 [cm3/molecule s] (T/298 K)-9.82 e-154649 [J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
RRK(M) extrapolation
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 900 | 4.48E-16 |
| 1000 | 1.26E-15 |
| 1100 | 2.68E-15 |
| 1200 | 4.66E-15 |
| 1300 | 7.00E-15 |
| 1400 | 9.39E-15 |
| 1500 | 1.16E-14 |
| 1600 | 1.33E-14 |
| 1700 | 1.46E-14 |
| 1800 | 1.52E-14 |
| 1900 | 1.54E-14 |
| 2000 | 1.52E-14 |
| 2100 | 1.47E-14 |
| 2200 | 1.39E-14 |
| 2300 | 1.30E-14 |
| 2400 | 1.20E-14 |
| 2500 | 1.09E-14 |