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Author(s):   Laufer, A.H.; Bass, A.M.
Title:   Photochemistry of Acetylene. Bimolecular Rate Constant for the Formation of Butadiyne and Reactions of Ethynyl Radicals
Journal:   J. Phys. Chem.
Volume:   83
Year:   1979
Reference type:   Journal article
Squib:   1979LAU/BAS310

Reaction:   H2 + ·C2HC2H2 +
Reaction order:   2
Reference reaction:   C2H2 + ·C2H1,3-Butadiyne +
Temperature:   298 K
Pressure:  0.93 bar
Rate expression:   1.52x10-13 [±1.06x10-14 cm3/molecule s]
Bath gas:   He
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Gas chromatography

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