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Accessibility information
Author(s):   Laufer, A.H.; Fahr, A.
Title:   Reactions and kinetics of unsaturated C2 hydrocarbon radicals
Journal:   Chem. Rev.
Volume:   104
Page(s):   2813 - 2832
Year:   2004
Reference type:   Journal article
Squib:   2004LAU/FAH2813-2832

Reaction:   H2 + ·C2HC2H2 +
Reaction order:   2
Temperature:   220 - 2200 K
Rate expression:   8.95x10-13 [cm3/molecule s] (T/298 K)(2.57±0.30) e-1081 [±1164 J/mole]/RT
Category:  Review
Data type:   Extensive literature review
Comments:   A factor and sign on Ea given in table in paper are incorrect

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
220 2.27E-13
300 5.91E-13
400 1.38E-12
500 2.61E-12
600 4.36E-12
700 6.68E-12
800 9.63E-12
900 1.33E-11
1000 1.77E-11
1100 2.28E-11
1200 2.88E-11
1300 3.57E-11
1400 4.35E-11
1500 5.23E-11
1600 6.20E-11
1700 7.28E-11
1800 8.47E-11
1900 9.77E-11
2000 1.12E-10
2100 1.27E-10
2200 1.44E-10