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Author(s):   Heicklen, J.
Title:   The decomposition of alkyl nitrites and the reactions of alkoxyl radicals
Journal:   Adv. Photochem.
Volume:   14
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988HEI177

Reaction:   C2H5C(CH3)2O(·) → C2H5COCH3 + ·CH3
Reaction order:   1
Temperature:   298 - 450 K
Rate expression:   1.0x1015 [s-1] e-78239 [J/mole]/RT
Category:  Review
Data type:   Extensive literature review

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
298 1.93E1
300 2.39E1
325 2.66E2
350 2.11E3
375 1.27E4
400 6.07E4
425 2.42E5
450 8.29E5