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Author(s):   Kerr, J.A.; Smith, B.J.A.; Trotman-Dickenson, A.F.; Young, J.C.
Title:   The abstraction of halogen atoms from alkyl halides by the trichlorosilyl radical
Journal:   J. Chem. Soc. A
Page(s):   510 - 513
Year:   1968
Reference type:   Journal article
Squib:   1968KER/SMI510-513

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1968KER/SMI510-513   CH3Br + SiCl3·CH3 + Silane, bromotrichloro-  373 - 573   0.27       -2.25E04      2
  Reference reaction:  CH3Cl + SiCl3·CH3 + SiCl4 2
  1968KER/SMI510-513   C2H5Br + SiCl3·C2H5 + Silane, bromotrichloro-  373 - 573   0.13       -2.67E04      2
  Reference reaction:  CH3Cl + SiCl3·CH3 + SiCl4 2
  1968KER/SMI510-513   C2H5Br + SiCl3·C2H5 + Silane, bromotrichloro-  387 - 521   0.21       1.31E04      2
  Reference reaction:  tert-C4H9Cl + SiCl3tert-C4H9 + SiCl4 2
  1968KER/SMI510-513   C2H5Cl + SiCl3·C2H5 + SiCl4  373 - 573   0.94       -4681      2
  Reference reaction:  CH3Cl + SiCl3·CH3 + SiCl4 2
  1968KER/SMI510-513   iso-C3H7Br + SiCl3 → Other Products + 2-C3H7  373 - 573   0.53       -2.94E04      2
  Reference reaction:  CH3Cl + SiCl3·CH3 + SiCl4 2
  1968KER/SMI510-513   iso-C3H7Br + SiCl32-C3H7 + Silane, bromotrichloro-  374 - 493   1.96       -6901      2
  Reference reaction:  CH3Br + SiCl3 → Other Products + ·CH3 2
  1968KER/SMI510-513   iso-C3H7Br + SiCl32-C3H7 + Silane, bromotrichloro-  373 - 573   0.53       1.48E07      2
  Reference reaction:  CH3Cl + SiCl3·CH3 + SiCl4 2
  1968KER/SMI510-513   iso-C3H7Br + SiCl32-C3H7 + Silane, bromotrichloro-  379 - 545   1.58       -2777      2
  Reference reaction:  C2H5Br + SiCl3 → Other Products + ·C2H5 2
  1968KER/SMI510-513   iso-C3H7Cl + SiCl32-C3H7 + SiCl4  386 - 521   1.76       -3176      2
  Reference reaction:  C2H5Cl + SiCl3·C2H5 + SiCl4 2
  1968KER/SMI510-513   iso-C3H7Cl + SiCl32-C3H7 + SiCl4  402 - 536   0.91       457      2
  Reference reaction:  sec-C4H9Cl + SiCl3sec-C4H9 + SiCl4 2
  1968KER/SMI510-513   iso-C3H7Cl + SiCl32-C3H7 + SiCl4  376 - 566   1.25       -2586      2
  Reference reaction:  1-C4H9Cl + SiCl31-C4H9 + SiCl4 2
  1968KER/SMI510-513   iso-C3H7Cl + SiCl32-C3H7 + SiCl4  350 - 4620   1.03       5729      2
  Reference reaction:  tert-C4H9Cl + SiCl3tert-C4H9 + SiCl4 2
  1968KER/SMI510-513   iso-C3H7Cl + SiCl32-C3H7 + SiCl4  370 - 566   1.45       -2336      2
  Reference reaction:  iso-C4H9Cl + SiCl3iso-C4H9 + SiCl4 2
  1968KER/SMI510-513   iso-C3H7Cl + SiCl32-C3H7 + SiCl4  361 - 525   1.78       -1754      2
  Reference reaction:  t-C4H9CH2Cl + SiCl3Neopentyl + SiCl4 2
  1968KER/SMI510-513   sec-C4H9Cl + SiCl3sec-C4H9 + SiCl4  373 - 573   1.82       -8314      2
  Reference reaction:  CH3Cl + SiCl3·CH3 + SiCl4 2
  1968KER/SMI510-513   1-C4H9Cl + SiCl31-C4H9 + SiCl4  373 - 573   1.32       -5271      2
  Reference reaction:  CH3Cl + SiCl3·CH3 + SiCl4 2
  1968KER/SMI510-513   tert-C4H9Br + SiCl3tert-C4H9 + Silane, bromotrichloro-  373 - 573   0.64       -3.32E04      2
  Reference reaction:  CH3Cl + SiCl3·CH3 + SiCl4 2
  1968KER/SMI510-513   tert-C4H9Br + SiCl3tert-C4H9 + Silane, bromotrichloro-  378 - 484   1.20       -3700      2
  Reference reaction:  iso-C3H7Br + SiCl3 → Other Products + 2-C3H7 2
  1968KER/SMI510-513   tert-C4H9Cl + SiCl3tert-C4H9 + SiCl4  373 - 573   1.60       -1.36E04      2
  Reference reaction:  CH3Cl + SiCl3·CH3 + SiCl4 2
  1968KER/SMI510-513   tert-C4H9Cl + SiCl3tert-C4H9 + SiCl4  373 - 573   1.65       -7865      2
  Reference reaction:  CH3Cl + SiCl3·CH3 + SiCl4 2
  1968KER/SMI510-513   iso-C4H9Cl + SiCl3iso-C4H9 + SiCl4  376 - 549   1.14       -5.52E06      2
  Reference reaction:  CH3Cl + SiCl3·CH3 + SiCl4 2
  1968KER/SMI510-513   t-C4H9CH2Cl + SiCl3Neopentyl + SiCl4  373 - 573   0.93       -6103      2
  Reference reaction:  CH3Cl + SiCl3·CH3 + SiCl4 2

Search returned 22 records.