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Title: Kinetics of the thermal isomerization of methylcyclopropane
Journal: J. Phys. Chem. A
Volume: 103
Page(s): 362 - 364
Year: 1999
Reference type: Journal article
Squib: 1999KAL/CHO362-364
Reaction:
Methylcyclopropane → (E)-2-C4H8
Reaction order:
1
Temperature:
695 - 1150
K
Pressure: 6.00E-2 - 1.00E-1 bar
Rate expression:
5.62x1014 [s-1] e-271883 [±1255 J/mole]/RT
Uncertainty:
1.14999998
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 695 | 2.07E-6 |
| 700 | 2.90E-6 |
| 725 | 1.45E-5 |
| 750 | 6.52E-5 |
| 775 | 2.66E-4 |
| 800 | 9.95E-4 |
| 825 | 3.43E-3 |
| 850 | 1.10E-2 |
| 875 | 3.31E-2 |
| 900 | 9.34E-2 |
| 925 | 2.49E-1 |
| 950 | 6.32E-1 |
| 975 | 1.53E0 |
| 1000 | 3.53E0 |
| 1025 | 7.85E0 |
| 1050 | 1.68E1 |
| 1075 | 3.46E1 |
| 1100 | 6.91E1 |
| 1125 | 1.34E2 |
| 1150 | 2.52E2 |