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Accessibility information
Author(s):   Kalra, B.L.; Cho, J.Y.; Lewis, D.K.
Title:   Kinetics of the thermal isomerization of methylcyclopropane
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   362 - 364
Year:   1999
Reference type:   Journal article
Squib:   1999KAL/CHO362-364

Reaction:   Methylcyclopropane(E)-2-C4H8
Reaction order:   1
Temperature:   695 - 1150 K
Pressure:  6.00E-2 - 1.00E-1 bar
Rate expression:   5.62x1014 [s-1] e-271883 [±1255 J/mole]/RT
Uncertainty:   1.14999998
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
695 2.07E-6
700 2.90E-6
725 1.45E-5
750 6.52E-5
775 2.66E-4
800 9.95E-4
825 3.43E-3
850 1.10E-2
875 3.31E-2
900 9.34E-2
925 2.49E-1
950 6.32E-1
975 1.53E0
1000 3.53E0
1025 7.85E0
1050 1.68E1
1075 3.46E1
1100 6.91E1
1125 1.34E2
1150 2.52E2