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Author(s):   Szwarc, M.
Title:   The C-H bond energy in toluene and xylenes
Journal:   J. Chem. Phys.
Volume:   16
Page(s):  
Year:   1948
Reference type:   Journal article
Squib:   1948SZW128

Reaction:   1,4-Dimethylbenzene → Products
Reaction order:   1
Temperature:   1020 - 1140 K
Pressure:  2.67E-3 - 2.00E-2 bar
Rate expression:   5.0x1013 [s-1] e-318444 [±6377 J/mole]/RT
Bath gas:   1,4-Dimethylbenzene
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1020 2.46E-3
1025 2.96E-3
1050 7.20E-3
1075 1.68E-2
1100 3.78E-2
1125 8.20E-2
1140 1.28E-1