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Title: A nonchain process for formation of methane and toluene in the pyrolytic hydrogenolysis of xylenes
Journal: J. Am. Chem. Soc.
Volume: 86
Page(s):
Year: 1964
Reference type: Journal article
Squib: 1964BUR/STR5065
Reaction:
1,4-Dimethylbenzene → Products
Reaction order:
1
Temperature:
949 - 1030
K
Rate expression:
3.79x107 [s-1] e-283523 [J/mole]/RT
Bath gas:
H2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 949 | 9.40E-9 |
| 950 | 9.77E-9 |
| 975 | 2.45E-8 |
| 1000 | 5.88E-8 |
| 1025 | 1.35E-7 |
| 1030 | 1.59E-7 |