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Accessibility information
Author(s):   Lindstedt, P.; Maurice, L.; Meyer, M.
Title:   Thermodynamic and Kinetic Issues in the Formation and Oxidation of Aromatic Species
Journal:   Faraday Discuss.
Volume:   119
Page(s):   409 - 432
Year:   2001
Reference type:   Journal article
Squib:   2001LIN/MAU409-432

Reaction:   C2H2 + Ethenyl,2-phenyl- → phenyl, cis-(Z)-2-(buta-1,3-dien-1-yl)
Reaction order:   2
Temperature:   900 - 1800 K
Pressure:  0.32 - 2.50 bar
Rate expression:   6.64x10-11 [cm3/molecule s] e-42300 [J/mole]/RT
Category:  Theory
Data type:   Derived from fitting to a complex mechanism

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
900 2.33E-13
950 3.14E-13
1000 4.10E-13
1050 5.22E-13
1100 6.51E-13
1150 7.96E-13
1200 9.57E-13
1250 1.13E-12
1300 1.33E-12
1350 1.53E-12
1400 1.75E-12
1450 1.99E-12
1500 2.24E-12
1550 2.49E-12
1600 2.76E-12
1650 3.04E-12
1700 3.33E-12
1750 3.63E-12
1800 3.93E-12