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Author(s):   Andersen, M.PS.; Hurley, M.D.; Wallington, T.J.
Title:   Kinetics of the gas phase reactions of chlorine atoms and OH radicals with CF3CBr = CH2 and CF3CF2CBr = CH2
Journal:   Chem. Phys. Lett.
Volume:   482
Page(s):   20 - 23
Year:   2009
Reference type:   Journal article
Squib:   2009AND/HUR20-23

Reaction:   ·Cl + CH2CBrCF2CF3 → Products
Reaction order:   2
Reference reaction:   C2H4 + ·Cl → Products
Reference reaction order:   2
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   9.16x10-1±4.1x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Long path length FTIR / smog chamber technique. Quoted uncertainties are two standard deviations from the least squares regressions together with the estimated uncertainties (±1% of the initial concentration) associated with the IR spectral analysis of the relative reactant and reference concentrations.

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