Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Scollard, D.J.; Treacy, J.J.; Sidebottom, H.W.; Balestra-Garcia, C.; Laverdet, G.; LeBras, G.; MacLeod, H.; Teton, S.
Title:   Rate constants for the reactions of hydroxyl radicals and chlorine atoms with halogenated aldehydes
Journal:   J. Phys. Chem.
Volume:   97
Page(s):   4683 - 4688
Year:   1993
Reference type:   Journal article
Squib:   1993SCO/TRE4683-4688

Reaction:   CHF2CHO + ·Cl → Products
Reaction order:   2
Reference reaction:   Acetone + ·ClCH3C(O)CH2(·) + HCl
Temperature:   298 K
Pressure:  0.97 - 1.00 bar
Rate expression:   5.6x10-12 [±1.01x10-12 cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.