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Author(s):   Wang, Y.;Liu, J.Y.;Li, Z.S.;Wang, L.;Wu, J.Y.;Sun, C.C.
Title:   Theoretical studies on dynamics and thermochemistry of the reactions CHClFCHO, CHF2CHO and CClF2CHO with the Cl atom
Journal:   Chem. Phys.
Volume:   324
Page(s):   609 - 621
Year:   2006
Reference type:   Journal article
Squib:   2006WAN/LIU609-621

Reaction:   CHF2CHO + ·Cl → Products
Reaction order:   2
Temperature:   220 - 2000 K
Rate expression:   1.92x10-12 [cm3/molecule s] (T/298 K)1.86 e2286 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
220 3.81E-12
300 4.86E-12
400 6.60E-12
500 8.71E-12
600 1.12E-11
700 1.39E-11
800 1.70E-11
900 2.04E-11
1000 2.40E-11
1100 2.80E-11
1200 3.22E-11
1300 3.67E-11
1400 4.15E-11
1500 4.66E-11
1600 5.19E-11
1700 5.76E-11
1800 6.34E-11
1900 6.96E-11
2000 7.60E-11