NIST Chemical Kinetics Database

Author(s):   Wasserman, E.P.; Moore, C.B.; Bergman, R.G.
Title:   Gas-phase rates of alkane C-H oxidative addition to a transient CpRh(CO) complex
Journal:   Science
Volume:   255
Page(s):   315 - 318
Year:   1992
Reference type:   Journal article
Squib:   1992WAS/MOO315-318

Reaction:   CO + Rhodium carbonyl (5-2,4-cyclopentadien-1-yl)- → (<.Eta.>5-cyclopentadienyl)dicarbonylrhodium
Reaction order:   2
Temperature:   298 K
Rate expression:   1.5x10^-10 [±2.99x10^-11 cm³/molecule s]
Bath gas:   Ar
Category: Experiment
Data type:   Absolute value measured directly
Excitation technique:   Direct photolysis
Analytical technique:   Vis-UV absorption

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