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Accessibility information
Author(s):   Alfano, A.I.
Title:   Gas-phase pyrolysis mechanism and kinetics of 3-chloroquadricyclane
Journal:   Int. J. Chem. Kinet.
Volume:   29
Page(s):   689 - 694
Year:   1997
Reference type:   Journal article
Squib:   1997ALF689-694

Reaction:   Tetracyclo[,704,6]heptane, 3-chloro- → Bicyclo[2.2.1]hepta-2,5-diene, 7-chloro-
Reaction order:   1
Temperature:   513 - 550 K
Pressure:  1.01 bar
Rate expression:   1.51x1015 [s-1] e-165458 [±6635 J/mole]/RT
Uncertainty:   5.0
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Time resolution:   In both real time and by end product analysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
513 2.15E-2
525 5.21E-2
550 2.92E-1