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Author(s):   Doering, W.v.E.; Franck-Neumann, M.; Hasselmann, D.; Kaye, R.L.
Title:   On the Mechanism of a Diels-Alder Reaction. Butadiene and Its Dimers
Journal:   J. Am. Chem. Soc.
Volume:   94
Year:   1972
Reference type:   Journal article
Squib:   1972DOE/FRA3833

Reaction:   (Z,Z)-1,5-Cyclooctadiene4-Vinylcyclohexene
Reaction order:   1
Temperature:   575 - 630 K
Pressure:  1.60E-3 - 1.87E-3 bar
Rate expression:   3.55x1015 [s-1] e-219502 [±4382 J/mole]/RT
Uncertainty:   2.19000006
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
575 4.08E-5
600 2.76E-4
625 1.61E-3
630 2.25E-3