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Author(s):   Shaw, R.; Trotman-Dickenson, A.F.
Title:   The reactions of methoxyl radicals
Journal:   Proc. Chem. Soc. London
Year:   1959
Reference type:   Journal article
Squib:   1959SHA/TRO61

Reaction:   iso-C4H10 + CH3 → Other Products + CH3OH
Reaction order:   2
Reference reaction:   C3H8 + CH3 → Other Products + CH3OH
Reference reaction order:   2
Temperature:   573 - 673 K
Rate expression:   2.4 e5438 [±8314472 J/mole]/RT
Uncertainty:   1.48000002
Bath gas:   NO2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
573 7.51E0
575 7.48E0
600 7.14E0
625 6.83E0
650 6.56E0
673 6.34E0