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Author(s):   Shaw, R.; Trotman-Dickenson, A.F.
Title:   The reactions of methoxyl radicals with alkanes
Journal:   J. Chem. Soc.
Year:   1960
Reference type:   Journal article
Squib:   1960SHA/TRO3210

Reaction:   iso-C4H10 + CH3 → Other Products + CH3OH
Reaction order:   2
Reference reaction:   C3H8 + CH3 → Other Products + CH3OH
Reference reaction order:   2
Temperature:   473 - 573 K
Rate expression:   5.37x10-1 e4639 [J/mole]/RT
Bath gas:   (CH3O)2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
473 1.75E0
475 1.74E0
500 1.64E0
525 1.55E0
550 1.48E0
573 1.42E0