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Author(s):   Manion, J.A.; Awan, I.A.
Title:   A Shock Tube Study of H Atom Addition to Cyclopentene
Journal:   Int. J. Chem. Kinet.
Volume:   50
Page(s):   225 - 242
Year:   2018
Reference type:   Journal article
Squib:   2018MAN/AWA225-242

Reaction:   Cyclopentene + C2H4 + ·CH2CH=CH2
Reaction order:   2
Reference reaction:   1,3,5-Trimethylbenzene + 1,3-Dimethylbenzene + ·CH3
Reference reaction order:   2
Temperature:   863 - 1167 K
Pressure:  1.60 - 3.70 bar
Rate expression:   6.37x10-1 e16587 [J/mole]/RT
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   The uncertainty is estimated at 10%.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
863 6.43E0
875 6.23E0
900 5.85E0
925 5.51E0
950 5.20E0
975 4.93E0
1000 4.68E0
1025 4.46E0
1050 4.26E0
1075 4.07E0
1100 3.91E0
1125 3.75E0
1150 3.61E0
1167 3.52E0