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Author(s):   Mayer-Figge, A.; Zabel, F.; Becker, K.H.
Title:   Thermal decomposition of CF3O2NO2
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   6587 - 6593
Year:   1996
Reference type:   Journal article
Squib:   1996MAY/ZAB6587-6593

Reaction:   CF3OONO2 → NO2 + CF3O2
Reaction order:   1
Temperature:   264 - 297 K
Rate expression:   1.49x1016 [s-1] e-98942 [±989 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   High or low pressure extrapolation
Pressure dependence:   Rate constant is high pressure limit
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
264 3.95E-4
275 2.40E-3
297 5.92E-2