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Title: Kinetics and equilibria of the reaction between bromine and ethyl ether. The C-H bond dissociation energy in ethyl ether
Journal: Int. J. Chem. Kinet.
Volume: 16
Page(s):
Year: 1984
Reference type: Journal article
Squib: 1984KON/BEN949
Reaction:
Diethyl ether + Br· → 2-C4H9O + HBr
Reaction order:
2
Temperature:
298 - 333
K
Rate expression:
1.05x10-10 [cm3/molecule s] e-16296 [±4240 J/mole]/RT
Uncertainty:
10.0
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 298 | 1.46E-13 |
| 300 | 1.52E-13 |
| 325 | 2.52E-13 |
| 333 | 2.91E-13 |