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Title: The decomposition of 2-pentyl and 3-pentyl radicals
Journal: Proc. Combust. Inst.
Volume: 34
Page(s): 537 - 545
Year: 2013
Book Title: ''
Editor: ''
Publisher: ''
Publisher address: ''
Comments: ''
Reference type: Journal article
Squib: 2013MAN/AWA537-545
Reaction:
2-(E)-C5H10 + H· → Products
Reaction order:
2
Temperature:
600 - 1700
K
Pressure: 0.10 - 1000 bar
Rate expression:
no rate data available
Category: Theory
Data type:
Transition state theory
Pressure dependence:
Rate constant is pressure dependent
Comments:
Using potential energy surface properties from the literature, rate constants and branching fractions for individual reaction channels were calculated for wide ranges of temperatures and pressures using transition state theory, RRKM, and master equation. Arrhenius expressions for individual pressures are presented in tabular and graphical formats.
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