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 Author(s):   Huynh, L.K.; Ratkiewicz, A.; Truong, T.N.
Title:   Kinetics of the hydrogen abstraction OH plus alkane -> H2O plus alkyl reaction class: An application of the reaction class transition state theory
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   473 - 484
Year:   2006
Reference type:   Journal article
Squib:   2006HUY/RAT473-484

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
    2006HUY/RAT473-484   CH4 + ·OH → ·CH3 + H2O  300 - 3000                  2
    2006HUY/RAT473-484   C2H6 + ·OH → ·C2H5 + H2O  300 - 3000                  2
    2006HUY/RAT473-484   C3H8 + ·OH → 1-C3H7 + H2O  300 - 3000                  2
    2006HUY/RAT473-484   C3H8 + ·OH → 2-C3H7 + H2O  300 - 3000                  2
    2006HUY/RAT473-484   1-C4H10 + ·OH → 1-C4H9 + H2O  300 - 3000                  2
    2006HUY/RAT473-484   1-C4H10 + ·OH → sec-C4H9 + H2O  300 - 3000                  2
    2006HUY/RAT473-484   iso-C4H10 + ·OH → iso-C4H9 + H2O  300 - 3000                  2
    2006HUY/RAT473-484   iso-C4H10 + ·OH → tert-C4H9 + H2O  300 - 3000                  2
    2006HUY/RAT473-484   n-C5H12 + ·OH → 1-C5H11 + H2O  300 - 3000                  2
    2006HUY/RAT473-484   n-C5H12 + ·OH → CH3CH2CH2CH(·)CH3 + H2O  300 - 3000                  2
    2006HUY/RAT473-484   n-C5H12 + ·OH → H2O + (CH3CH2)2CH  300 - 3000                  2
    2006HUY/RAT473-484   iso-C5H12 + ·OH → ·CH2CH(CH3)CH2CH3 + H2O  300 - 3000                  2
    2006HUY/RAT473-484   iso-C5H12 + ·OH → (CH3)2C(·)CH2CH3 + H2O  300 - 3000                  2
    2006HUY/RAT473-484   iso-C5H12 + ·OH → (CH3)2CHCH(·)CH3 + H2O  300 - 3000                  2
    2006HUY/RAT473-484   iso-C5H12 + ·OH → (CH3)2CHCH2CH2· + H2O  300 - 3000                  2
    2006HUY/RAT473-484   (CH3)2CH(CH2)2CH3 + ·OH → H2O + (CH3)2CHCH(·)C2H5  300 - 3000                  2
    2006HUY/RAT473-484   Pentane, 2,4-dimethyl- + ·OH → (CH3)2CHCH(·)CH(CH3)2 + H2O  300 - 3000                  2
    2006HUY/RAT473-484   (C2H5)2CHCH3 + ·OH → H2O + (C2H5)2(CH3)C  300 - 3000                  2
    2006HUY/RAT473-484   3-Ethylpentane + ·OH → CH3CH2C(·)(CH2CH3)CH2CH3 + H2O  300 - 3000                  2
Search returned 19 records.