Author(s):   Osborne, D.A.; Waddington, D.J.
Title:   Reactions of oxygenated radicals in the gas phase. Part 14. Reactions of t-butylperoxyl radicals
Journal:   J. Chem. Soc. Perkin Trans. 2
Page(s):
Year:   1984
Reference type:   Journal article
Squib:   1984OSB/WAD1861

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	k(298.00 K)	Order
1984OSB/WAD1861	(tert-C₄H₉N)2 → tert-C₄H₉ + tert-C₄H₉ + N₂	453	4.66E-05		1
1984OSB/WAD1861	tert-C₄H₉ + tert-C₄H₉ → iso-C₄H₁₀ + Isobutene	343 - 453	2.67		2
Reference reaction: tert-C₄H₉ + tert-C₄H₉ → 2,2,3,3-Tetramethylbutane				2

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