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Title: Atmospheric degradation of alkylfurans with chlorine atoms: Product and mechanistic study
Journal: Atmos. Environ.
Volume: 43
Page(s): 2804 - 2813
Year: 2009
Reference type: Journal article
Squib: 2009VIL/CAB2804-2813
Reaction:
2-Methylfuran + ·Cl → Products
Reaction order:
2
Temperature:
296
K
Pressure: 1.00 bar
Rate expression:
no rate data available
Category: Experiment
Data type:
Mechanistic information only
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Fourier transform (FTIR)
Comments:
Products of the reactions of chlorine atoms with 2-methylfuran were studied in smog chambers using gas chromatography, GC/MS, and FTIR spectroscopy. Evidence for the H-atom abstraction from the alkyl group was obtained. No rate constant values were reported.
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