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 Author(s):   Westmoreland, P.R.; Dean, A.M.; Howard, J.B.; Longwell, J.P.
Title:   Forming benzene in flames by chemically activated isomerization
Journal:   J. Phys. Chem.
Volume:   93
Page(s):   8171 - 8180
Year:   1989
Reference type:   Journal article
Squib:   1989WES/DEA8171-8180

Reaction:   1,3-Butadiene + C2H3 → 1,3-Cyclohexadiene + H·
Reaction order:   2
Temperature:   400 - 1600 K
Pressure:  1.01 bar
Rate expression:   4.45x10-19 [cm3/molecule s] (T/298 K)6.39 e-10227 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
400 1.35E-19
500 1.04E-18
600 5.01E-18
700 1.80E-17
800 5.26E-17
900 1.32E-16
1000 2.98E-16
1100 6.12E-16
1200 1.17E-15
1300 2.12E-15
1400 3.63E-15
1500 5.99E-15
1600 9.52E-15